有机化学第二版 - 夏百根 - 黄乾明 - 主编 - 课后答案 - 图文

OHA:CH3CH2-C-CH=CH2CH37、

OHB:CH3CH2-C-CH2-CH3CH3

8、

CH3-CH2-CH=CH-CH2-CH3H2OH2SO4*CH3-CH2-CH-CH2-CH2-CH3OHAKMnO4/OH-BC2H5HOHCH3-CH2-CH-CH-CH2-CH3OHOHC的构型为:HOHC2H5C

第六章 卤代烃习题参考答案 1、(1)2-甲基-1-氯丙烷(伯卤代烷) (2)2-甲基2-溴丁烷(叔卤代烷)

(3)2,2-二甲基4-溴戊烷(仲卤代烷) (4)Z-2-甲基-1-溴-2-戊烯(烯丙基型)

(5)Z(顺)-3-甲基-2-氯-2-戊烯(乙烯型) (6)3-甲基-4-溴-1-丁烯(隔离型卤代烃) (7)对-氯甲苯(乙烯型) (8)1-苯基-1-溴丙烷(烯丙基型) 2、(1) (2) (3) (4)

BrBrCH3-CH-CH-CH3CH3ClCH3CH3-C C CH2-CH3ClCH=CH-CH2CH=CH-CH2Br

CH3Cl

(5) (6) (7) (8)

H3CClClHC=CClC=CHH

CH3C=CCH3HCH2BrH3、(1)

CH3Cl

CH2ClCl

ClClabcCH3d

abcd(2)

AgNO3醇白:b快 a慢褪色:d无沉淀;c, dKMnO4H+CH3不褪色:c

CH3-CH-CH-CH3CH3ClCH2=CHClCH2=CH-C-CH3Claabc

(3)

CH2=CH-CH-CH3ClCH2=CH-CH-CH3IAgNO3醇b白:快cc白:慢a无沉淀:b

AgNO3醇CH2=CH-CH-CH3先有黄色沉淀:ICH2=CH-CH-CH3先有白色沉淀:Cl

4、

(1)

CH2-CH-CH2CH3BrCH3>CH3-CH-CH-CH3CH3Br>BrCH3-C-CH2CH3CH3

(2)

BrCH3-C-CH3CH3

>CH3-CH2-CH-CH3Br>CH2-CH2-CH2CH3Br(3)

CH2-CH2-CH2CH3I

CH2-CH2-CH2CH3Cl>CH2-CH2-CH2CH3Br>(4)

BrCH3-C-CH2CH3CH3>CH3-CH-CH-CH3CH3Br>BrCH2-CH-CH2CH3CH35、

(1)

CH3-CH-CH-CH3NaOHCH3Cl乙醇,CH3-C=CH-CH3CH3Br2

BrCH3-C-CH-CH3NaOHCH3Br乙醇,CH2=C-CH=CH2CH3(2)

ClCH2Cl

+NaCN乙醇ClCH2CNH2OH+ClCH2COOH(3)

CH2Br+Mg无水乙醚CH2MgBr(1)CO2(2)H2OCH2COOH

(4)

CH-CH3NaOH乙醇,BrCH=CH2HBr过氧化物CH2-CH2BrCH3ONa乙醇

CH2-CH2OCH3

(5)

CH3BrNaOH乙醇,CH3KMnO4H+OOCH3-C-CH2-CH2-CH2-C-OH 6、 (1) CH2=CH2Br2NaCNBr-CH2-CH2-Br乙醇NC-CH2-CH2-CNH2OH+

HOOC-CH2CH2-COOH(2) CH3-CH2-CH-CH3NaOH乙醇,BrCH3-CH=CH-CH3KMnO4H+CH3COOH (3)CH2=CH2(4)

CH3-CH2CH2-ClHClCH3-CH2ClNa

NH3CH3-CH-CH3NH3CH3-CH2-CH2CH3HClNaOH乙醇,CH3-CH=CH2CH3-CH-CH3Cl(5)

CH2-CH-CH3BrH2OH+NaOH乙醇,CH2=C-CH3CH3HBrCH3BrNaCNCH3-C-CH3乙醇CH3CNCH3-C-CH3CH3

COOHCH3-C-CH3CH3HBr过氧化物(6)

CH3CH3-C=CH2

CH3CH3-CH-CH2BrNaCN乙醇CH3H2OCH3-CH-CH2CNH+CH3-CH-CH2COOH HBrBrCH3-C-CH2-CH3CH3CH37、

CH3-CH-CH-CH3NaOHCH3Br乙醇,CH3-C=CH-CH3CH3ANaOH乙醇,CH3BCH3-C=CH-CH3KMnO4H+CH3-C=OCH3+CCH3COOH8、

A、CH3CHCH=CH2BrB、CH3CH-CHCH2BrBrBrC、CH2=CH-CH=CH2

第七章 醇 酚 醚习题参考答案 1、

(1)4-基-2-己醇 (2)2-甲基-2-丙烯基-3-戊烯-1-醇 (3)2,4-己二醇 (4)3-环己烯-1-醇 (5)4-苯基-2-戊醇 (6)E-5-甲基-4-庚烯-3-醇

(7)4-甲基苯酚 (8)对甲氧基苯甲醇 (9)苯乙醚 (10)1,2-环氧丁烷 2、

(1) (2) (3) (4) (5)

CH3CH3-C-OHOHH3COCH2OHOH(6)

CH3 CH3 H3C

CH2OH

COOHOH

3、

(1)(CH3)3C-OH+HBr(2)

OH+HCl(浓)(CH3)3C-Br无水ZnCl2+H2OCl

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