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(2) ¶¨Ñ¹¹ý³Ì£¬p = ³£Á¿£¬ Q?MCp(T2?T1)=1.04¡Á103 J Mmol ?EÓë(1) Ïàͬ£® W = Q ???E£½417 J
(3) Q =0£¬?EÓë(1) ͬ W = ??E=?623 J (¸ººÅ±íʾÍâ½ç×ö¹¦) 151£®½â£º
(1) A¡úB£º W11?2(pB?pA)(VB?VA)=200 J£®
¦¤E1=??CV (TB£TA)=3(pBVB£pAVA) /2=750 J
Q=W1+¦¤E1£½950 J£®
B¡úC£º W2 =0
¦¤E2 =??CV (TC£TB)=3( pCVC£pBVB ) /2 =£600 J£®
Q2 =W2+¦¤E2£½£600 J£®
C¡úA£º W3 = pA (VA£VC)=£100 J£®
?E3??CV(TA?TC)?32(pAVA?pCVC)??150 J£® Q3 =W3+¦¤E3£½£250 J
(2) W= W1 +W2 +W3=100 J£® Q= Q1 +Q2 +Q3 =100 J 152£®½â£º
(1) ¶Ô¿¨ÅµÑ»·ÓУº T1 / T2 = Q1 /Q2
¡à T2 = T1Q2 /Q1 = 320 K ¼´£ºµÍÎÂÈÈÔ´µÄζÈΪ 320 K£® (2) ÈÈ»úЧÂÊ£º ??1?Q2Q?20% 1153£®½â£º
(1) ??WQ1?QQ?2?T1?T2T 1Q11 QT11?WTT ÇÒ Q2?T2
1?2Q1T1¡à Q2 = T2 Q1 /T1
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¼´ Q2?T1T?T2W?T2£½24000 J
1?T2T1T1?T2ÓÉÓÚµÚ¶þÑ»·ÎüÈÈ Q1??W??Q2??W??Q2 ( ¡ß Q2??Q2) ???W?/Q1??29.4£¥ (2) TT21??1????425 K 154£®½â£º
ÓÉͼµÃ pA£½400 Pa£¬ pB£½pC£½100 Pa£¬
VA£½VB£½2 m3£¬VC£½6 m3£® (1) C¡úAΪµÈÌå¹ý³Ì£¬¾Ý·½³ÌpA /TA = pC /TC
TC = TA pC / pA =75 K
B¡úCΪµÈѹ¹ý³Ì£¬¾Ý·½³Ì VB /TB =VC TC
TB = TC VB / VC =225 K
(2) ¸ù¾ÝÀíÏëÆøÌå״̬·½³ÌÇó³öÆøÌåµÄÎïÖʵÄÁ¿(¼´Ä¦¶ûÊý)??Ϊ
???? pA VA??RTA ???????mol ÓÉ?£½1.4Öª¸ÃÆøÌåΪ˫Ô×Ó·Ö×ÓÆøÌ壬C5V?2R£¬C7P?2R B¡úCµÈѹ¹ý³ÌÎüÈÈ Q72?2?R(TC?TB)??1400 J£® C¡úAµÈÌå¹ý³ÌÎüÈÈ Q53?2?R(TA?TC)?1500 J£® ¦¤E =0£¬Õû¸öÑ»·¹ý³Ì¾»ÎüÈÈ
Q?W?12(pA?pC)(VB?VC)?600 J£® ¡à A¡úB¹ý³Ì¾»ÎüÈÈ£º Q1=Q£Q2£Q3=500 J 155£®½â£º
(1) Ta = paV2/R£½400 K Tb = pbV1/R£½636 K Tc = pcV1/R£½800 K Td = pdV2/R£½504 K
(2) Ec =(i/2)RTc£½9.97¡Á103 J
(3) b£cµÈÌåÎüÈÈ Q1=CV(Tc?Tb)£½2.044¡Á103 J
d£aµÈÌå·ÅÈÈ Q2=CV(Td?Ta)£½1.296¡Á103 J
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W=Q1?Q2£½0.748¡Á103 J 156£®½â£º
(1) ¹ý³ÌabÓëbcΪÎüÈȹý³Ì£¬ ÎüÈÈ×ܺÍΪ
Q1=CV(Tb£Ta)+Cp(Tc£Tb)?35(pbVb?paVa)?(pcVc?pbVb)=800 J 22 (2) Ñ»·¹ý³Ì¶ÔÍâËù×÷×ܹ¦ÎªÍ¼ÖоØÐÎÃæ»ý W = pb(Vc£Vb)£pd(Vd £Va) =100 J
(3)
Ta=paVa/R£¬Tc = pcVc/R£¬ Tb = pbVb /R£¬Td = pdVd/R£¬
TaTc = (paVa pcVc)/R2=(12¡Á104)/R2 TbTd = (pbVb pdVd)/R2=(12¡Á104)/R2
¡à TaTc=TbTd 157£®½â£º
ÓÉͼ£¬pA=300 Pa£¬pB = pC =100 Pa£»VA=VC=1 m3£¬VB =3 m3£® (1) C¡úAΪµÈÌå¹ý³Ì£¬¾Ý·½³ÌpA/TA= pC /TC
TC = TA pC / pA =100 K£® B¡úCΪµÈѹ¹ý³Ì£¬¾Ý·½³ÌVB/TB=VC/TCµÃ TB=TCVB/VC=300 K£®
(2) ¸÷¹ý³ÌÖÐÆøÌåËù×÷µÄ¹¦·Ö±ðΪ A¡úB£º W1?12(pA?pB)(VB?VC)=400 J£® B¡úC£º W2 = pB (VC£VB ) = ?200 J£® C¡úA£º W3 =0
(3) Õû¸öÑ»·¹ý³ÌÖÐÆøÌåËù×÷×ܹ¦Îª
W= W1 +W2 +W3 =200 J£®
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Q =W+¦¤E =200 J.
158£®½â£º
(1) Q31?RT1ln(V2/V1)?5.35?10 J (2) ??1?T2T?0.25. 1 W??Q31?1.34?10 J (3) Q2?Q1?W?4.01?103 J 159£®½â£º
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¸ù¾Ý¾øÈȹý³Ì·½³Ì£º p1£
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¸ÕÐÔË«Ô×Ó·Ö×Ó ?????? £¬´úÈëÉÏʽ²¢´úÈëÌâ¸øÊý¾Ý£¬µÃ T2 =410 K 160£®½â£º
(1) ¸ù¾Ý¾øÈȹý³Ì·½³Ì p??1T???C
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T2?(p2)(??1)/?Tp 11¡à Tp2(?2?T1(p)?1)/? 1º¤Îªµ¥Ô×Ó·Ö×Ó£¬??5/3 ¡à T2=1200 K (2) n?p2?1.96?1026 m?3kT 2
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