高考化学专题复习有机化合物的推断题综合题附答案 - 百度文库

3CH3COOHCH3CH2OHӦĻѧʽ

ŨCH3COOH+CH3CH2OHCH3COOCH2CH3+H2OʴΪ

CH3COOH+CH3CH2OHCH3COOCH2CH3+H2O

Ũ

5ȩƱᡢȻƷԭϡգ (1)ȩеĹΪ______

(2)ͭ˿ڿձںѸҴУ۲쵽ͭ˿______βŵ̼ζ˵______ɡ

(3)дȩĻѧӦʽ______Ӧʾȩ______ԡ (4)֪ҲܷӦijҺпܻȩͨʵ֤ǷȩдҪ________________

(5)֪лѧнڹŵĵһ̼ԭӳΪCCϵHͳΪHȩĦHϻãԺһȩʻмӳɣǻȩ磺

һϩΪԭƱCH3CH2CH2CH2OHĺϳ·(޻Լѡ)

?? B???????Ŀ_________(ϳ·߳õıʾʽΪA?????ӦӦ)

𰸡ȩ ɺڱ ȩ

?ӦԼӦԼCH3CHO+2Ag?NH3?2OH?CH3COONH4+3NH3?+2Ag+H2O ԭ ȡ

üҺƺ󣻢ȡҺҺˮԡȣȩ

(1)ȩĽṹʽCH3CHO

(2)ͭ˿ڿձΪɫCuOѸҴУӦ

?CH3CH2OH+CuO?CH3CHO+Cu+H2Oȩд̼ζ

(3)ȩȩܷӦ

(4)ȷȩҺȩ

(5)ϩˮӳҴҴΪȩȩCH3CH(OH)CH2CHOCH3CH(OH)CH2CHOCH3CH=CHCHOCH3CH(OH)CH2CHOӳɷӦCH3CH2CH2CH2OH ⡿

(1)ȩĽṹʽCH3CHOΪȩ

(2)ͭ˿ڿձΪɫCuOѸҴУӦ

?CH3CH2OH+CuO?CH3CHO+Cu+H2OԹ۲쵽ͭ˿ɺڱ죻ŵ̼

ζ˵ȩɣ

(3)ȩȩܷӦȩĻѧӦʽ

?CH3CHO+2Ag?NH3?2OH?CH3COONH4+3NH3?+2Ag+H2O ȩ

ӦȩĻԭԣ

(4)֤ǷȩļҪ:ȡüҺƺ󣻢ȡҺҺˮԡȣȩ

(5) ϩˮӳҴҴΪȩȩCH3CH(OH)CH2CHOCH3CH(OH)CH2CHOCH3CH=CHCHOCH3CH(OH)CH2CHOӳɷӦCH3CH2CH2CH2OHϩΪԭƱCH3CH2CH2CH2OHĺϳ·ǣ

6ʯȲϩɹҵϩķ

2?CH2=CHCl(HgCl2/̿߻)ijѧϰСͬӦԭΪHCCH+HCl?????100-180HgCl/̿ѧװòⶨ÷ӦȲת(Ӧ)̨гδ(֪CH2?CHCl۵Ϊ-159.8棬еΪ-134档ȲϩȻҺA)

1װõ˳Ϊ(ͷΪ

):__________________________h__________________________________ 2װó˾Ȼ֮⣬__________________á

3װзӦĻѧʽΪ_________________________________ 4ʵõĵʯк1.28gCaC2װв0.02molHCl塣ѡõͲݻϺ_______(ĸ) A500ml B1000ml C2000ml

5ٶڱ׼״²øռҺAΪ672ml(Բ)ȲתΪ_________

𰸡b f e g c d j ۲

CaC2?2H2O?Ca(OH)2?C2H2? B 50%

1ݷӦ֪̿װҵΪȡȲװöȥʺװиԼʹϾȣװñзӦϩװü͸ⶨݴװã

2װƵõȲװöȥʺװüƵõHClװиԼʹϾȺװñзӦϩɴȷװã

3װзķӦΪʯˮȲƣ 4̼ƵʵΪ

1.28g?0.02molɼ0.02molHClӦϩ

64g/molڱ׼״µٿȲȫתȲϩȻҺA ݴѡͲ

1.28g?0.02molɼȲ0.02molHCl壨5̼ƵʵΪ

64g/molȲϩȻҺAɴ˿ɼȲתʡ ⡿

1ݸװͼ֪װȡȻ⣬װȡȲװϩƱװڳȥȲеʣװڸԼʹϾȣ͸ڲⶨװõ˳Ϊbfeg cdj

2װڸԼʹϾȵȣ

3̼ˮӦĻѧʽΪCaC2?2H2O?Ca(OH)2?C2H2?

1.28g?0.02mol0.02molHClӦϩڱ׼4̼ƵʵΪ

64g/mol״µΪ0.02mol22.4L/mol=0.448L=448mlȲȫתȲϩȻҺA Ӧѡȡ1000mLͲ 5̼ƵʵΪ

1.28g?0.02molȲ0.02molHClڱ

64g/mol׼״Ϊ(0.02mol+0.02mol) 22.4L/mol=0.896L=896mLȲϩȻ

ҺAȲתΪ㾦

224mL?100?50

448mL漰˳⣬ڷʱҪע˼ά̣

7̽ʵĽṹڶʵʽо 1 кȻ____ĸ a

b

c

ʷԭӴͬһƽ____ĸ a b ϩ c ״

ȩᣬӦѡ____ĸ a NaOHҺ b HClҺ c NaHCO3Һ 2дѧʽдӦͣ

ټڹµķӦдһ__________ ________Ӧ ϩʹˮȻ̼Һɫ___________________Ӧ ȵͭ˿ηزҴУ___________________Ӧ

3֪лAIJһҵʯͻչˮƽAΪҪԭϺϳϳ·ͼʾ

٣Bйŵ________Dйŵ_____________ӦٵķӦ___________Ӧ

ڣӦݵĻѧʽ_____________

4ijͬѧͼʾʵװȡʵԹܼϲΪ͸ġˮ״Һ塣ʵԹܼԼΪ________________ĸ

A кҴ B кᲢղҴ

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