解：

(1)CH3CH2CH2CH2OH(3)CH3CH2CH2CH2MgBr(5)CH3CH2CH2CH2I(7)CH3CH2CH2CH2CCCH3(9)CH3CH2CH2CH2OC2H5(11)CH3(CH2)3ONO2+ AgBr(2)CH3CH2CHCH2

(4)CH3CH2CH2CH2D(6)CH3CH2CH2CH2CH3(8)CH3CH2CH2CH2NHCH3(10)CH3CH2CH2CH2CN(12)CH3(CH2)3OOCCH3+ AgBr(六) 完成下列反应式：

解：红色括号中为各小题所要求填充的内容。 (1)

OCH3CH3CCH2ICH3CH3COOAgOCCH3CH3CCH2CH3+CH3CH3(主要产物)

CH3OCCH2OCCH3 CH3(次要产物)NaI(2)

BrBrBr丙酮BrI

H3C(3)

H3CNaCNH+H3CCH3CH3CH3HHHDMFHHCNHH

(主要产物)BrDHNaOC2H5C2H5OHCH3O-(次要产物)

(4)

CH3HHCH3H(5)

(R)-CH3CHBrCH2CH3(S)-CH3CHCH2CH3OCH3

(6) HOCH2CH2CH2CH2ClNaOHH2OO

CH3(7) (S)BrCH3CN -COOC2H5H(S)HCNCOOC2H5

C2H5OCOBr(S)NH3CN -COOC2H5NCCBr#SN2NCCOOC2H5CHCH3解释：

HH3CC

HCH3(S)(8) CH3CH2CH2BrCH3CH2CH2NH2

NaNH2CH3CH=CH2

(9)

BrCH3(CH2)2CHCH3NaOHCH3CH2CH=CHCH3 + CH3CH2CH2CH=CH2 + CH3CH2CH2CHCH3OH(10) F(11)

Mg纯醚

BrFMgBr

CH2INaCNCH2CNCH3(CH2)3Li(12)

Ph(13)

HBrCl2h?PhLiBrBrICH3ICH2Cl(A)HCCNaICH2CCH (B)BrHgSO4dil H2SO4Br2h?OICH2CCH3 (C)CHCH3(A)BrNaOHC2H5OH(14)

ClCH2CH3ClClCH=CH2(B)

HBr过氧化物ClCH2CH2Br(C)CH3ONaCH3OHNaCNClCH2CH2CN(D)

Br(15)

ClClNO2ClOCH3NO2(A)Br2FeClOCH3NO2(B)