3.CH CCH3CH3OH-冷、稀+KMnO4H＋

CH2CH CH2+HBr4.（过量）5.(CH3)CHC CH+Cu(NH3)2Cl

H＋6.(CH3)3CC2H5+KMnO47.8.ClC CH+H2OHgSO4-H2SO4AlCl3 +OHCH3CHCH2ClCH3

9.CH2CH310.+稀HNO3Fe

+Br2CH3h?11.BrCHCHCH2Cl+KCN（过量）12.CH3Cl KOH-C2H5OHCHCHCH2CH313.OHOH浓H2SO4 CH3CH2I14.ClNaOH

+ K2Cr2O7OH浓H2SO415.OCH316.

+HI 17.+CH3CH3O3Zn/H2O18.CO+HCNH3O+ 19.CHO+Ag(NH3)2OH

20.O+H2NOHOH

21.COOH+NaHCO3

22.CH3CHOH-2CHO稀CHO23.+HCHO浓OH-O

C24.O+CH3OHCO25.HCOOH+CH浓H2SO 43CHCH3O18HCOOH

26.+27.CHH 3OCH3O+O2CH(OCH3)2 28.CH3CCH2COOCH2CH3+Br2H2OCOOH 29.PCl3NH330.CH2 CHCOOH+HBr 31.CHCH2COOHOH

32.+NaOHH2OO33.OCH3CH2CHCH3NaOH OH+I2F

34.CH3CHCOOHNO2NH+2NO2

Br2/NaOH

CH335.NH+CH3I(过量）湿Ag2O36.CH3CHCH2CHCH3+NaNO2NH2OHHCl

37.N浓H2SO4/SO3OH

OO38.H2N C CH2C ClN2Cl+N(CH3)2

0~5℃39.N2Cl+

40.+CuClNHNH2

41.OHOCH2+OOHOHOH(过量）

42.+CH3OH干HCl43.OHH2NCH2COOH+HCHOOONH2HOCH2

44.CH3CHCNHCNH2 +H2OOOH45.OHOHOH+Br2H2O

SO3HPCl5NH346.CH3OCC

NH3KOHRX47.OO

O48.C+CHCHMgBr49.CH3CHCHCC50.CH2CHCH251.CH3CHCHCH+Br2(1mol)+Br2(1mol)

-80℃

CH2+ HBr40℃COOH

52.OCH2OH

53.CH3CH2CCH2CH2CHO+NaHSO3(过量）54.55.CH2C(CH3)2Cl+H2OBrOH-56.OCClClCH2CHCH(CH3)2KOH / C2H5OHBr+C2H5OH(过量)HClZnCl257.(CH3)3CCHCH3OH58.CH3CHCHCH2CH3ClClKOH / C2H5OH

浓H2SO4160℃59.

四、用简便的化学方法鉴别下列各组化合物

1.烯丙基溴、丙烯基溴、甲醇和乙醇 2. 1－戊醇、1－戊硫醇、正丙醚 3. 1－丁炔、2－丁炔和甲基环丙烷 4.甲苯、苯乙烯、苯乙炔和叔丁基苯 5.甲酸、草酸、葡萄糖和果糖 6. α－氨基丙酸、β－氨基丙酸和苯胺 7.果糖、蔗糖、麦芽糖 8.吡啶、β－甲基吡啶和糠醛 9.2－戊酮、3－戊酮和环戊酮 10.淀粉、蛋白质、甘氨酸

11.甲酸、甲醛、乙醛和苯甲醛 12.己醛、2－己酮、己醛糖和己酮糖 13.苯胺、苯酚、环己醇和环己酮 14.苄胺、苯胺、甘氨酸、乙酰胺 15.甲苯、苯酚和2,4,6－三硝基苯酚 16.RNA、DNA、蛋白质和油脂 17.苯甲醚、苯甲醇、邻甲苯酚 18. 乙酰氯、乙酸酐、乙酸乙酯