(?(Hg2+/Hg)=0.857 v£¬(?(Fe3+/Fe2£«)=0.771 v£¬Ôò¦Â4 ( HgBr4)Ϊ**** £¨ £© A¡¢8.52¡Á1010 B¡¢1.16¡Á1018 C¡¢7.21¡Á1021 D¡¢6.84¡Á1028

38£®ÏÂÊöÅäºÏÎï¸ß×ÔÐý»òµÍ×ÔÐýµÄÅжϴíÎóµÄÊÇ*** £¨ £© A¡¢[ Fe(H2O)6 ] 3£« ¸ß×ÔÐý B¡¢[ Ni(CN)4 ] 2£­ µÍ×ÔÐý

C¡¢[ Fe(CN)6 ] 4£­ µÍ×ÔÐý D¡¢[ Co(NH3)6 ] 3£« ¸ß×ÔÐý 39£®ÏÂÁÐÅäÀë×ӵĿռ乹ÐÍΪËÄÃæÌåµÄÊÇ* £¨ £© A¡¢[ Zn(NH3)4 ] 2£« B¡¢[ Cu(NH3)4 ] 2£«

C¡¢[ Ni(CN)4 ] 2£­ D¡¢[ PtCl4 ] 2£­ 40£®ÏÂÁÐÀë×ÓÔÚÐγɸß×ÔÐýÐÍÅäºÏÎïʱ£¬´Å¾Ø×î´óµÄÊÇ*** £¨ £© A¡¢V2£« B¡¢Ti4£« C¡¢Mn2£« D¡¢ Co2

41£®ÓÉÏÂÁÐÊý¾Ý¿ÉÈ·¶¨ [ Ag( S2O3)2 ] 3£­ µÄÎȶ¨³£Êý KÎÈ µÈÓÚ**** £¨ £© ¢Ù Ag£« £« e£­ £½ Ag ?£½ 0.799 v

¦¨

£«

¦¨¦¨

2? ¢Ú [ Ag( S2O3)2 ] 3£­£« e£­ £½ Ag £« 2 S2O3 2£­ ?£½ 0.017 v

¦¨

A¡¢1.6¡Á1013 B¡¢3.4¡Á1015 C¡¢4.2¡Á1018 D¡¢8.7¡Á1021 42£®ÅäºÏÎï [ Pt(NH3)4 ][CuCl4 ] Óë [ PtCl4 ][Cu(NH3)4 ] »¥Îª*** £¨ £© A¡¢¼¸ºÎÒì¹¹ B¡¢µçÀëÒì¹¹ C¡¢Ðý¹âÒì¹¹ D¡¢ÅäλÒì¹¹

43£®ÓÐËÄÖÖÅäºÏÎïÈÜÒº £¬ÔÚŨ¶È£¨mol?L£­1£©Ïàͬʱµ¼µçÄÜÁ¦ÓÉ´óµ½Ð¡µÄ˳ÐòÕýÈ·µÄÊÇ***

£¨ £©

a¡¢Cr( NH3 )4Cl3 b ¡¢Pt( NH3 )6Cl4 c ¡¢K2PtCl6 d ¡¢Co( NH3 )6Cl3

A¡¢a > b > c > d B¡¢b > c > d >a C¡¢c > d > a > b D¡¢b > d > c >a

44£®ÏÂÁи÷×éÅäÀë×ÓÖÐ £¬¼¸ºÎ¹¹ÐÍÏàͬµÄÒ»×éÊÇ*** £¨ £© A¡¢[ Cd(CN)4 ] 2£­ ºÍ [PtCl4 ] 2£­ B¡¢[ Ni(CN)4 ] 2£­ ºÍ [Cu(NH3)4 ] 2£« C¡¢[ Zn(CN)4 ] 2£­ ºÍ [PtCl4 ] 2£­ D¡¢[PtCl6 ] 2£­ ºÍ [FeCl4 ]£­ 45£®ÏÂÁи÷×éÅäÀë×ÓÖÐ £¬ÊôÓÚ¸ß×ÔÐýÐ͵ÄÒ»×éÊÇ*** £¨ £© A¡¢[ Cu(H2O)4 ] 2£«ºÍ [Zn(CN)4 ] 2£­ B¡¢[ Fe(H2O)6 ] 2£«ºÍ [Mn(NCS)6 ] 4£­ C¡¢[ Fe(CN)6 ] 3£­ ºÍ [PtCl6 ] 2£­ D¡¢[ ZnCl4 ] 2£­ ºÍ [Ni(CN)4 ] 2£­ 46£®ÏÂÁÐÅäºÏÎÀë×Ó£©ÖÐ £¬¾ßÓÐ 3 ÖÖ¼¸ºÎÒì¹¹ÌåµÄÊÇ*** £¨ £© A¡¢[ Cr(NH3)3Cl3 ] B¡¢[ Zn(en)Cl2 ]

C¡¢[ PtCl2(NO2)2(NH3)2 ] D¡¢[ Co(NH3)2(en)Cl2 ]£«

47£®K4[Fe(CN)6 ] ÊÇ** £¨ £© A¡¢·´´ÅÐÔ B¡¢Ë³´ÅÐÔ C¡¢Ìú´ÅÐÔ D¡¢·´Ìú´ÅÐÔ 48£®¸ù¾Ý¾§Ì峡ÀíÂÛ £¬Ðγɸß×ÔÐýÅäºÏÎïµÄÀíÂÛÅоÝÊÇ** £¨ £© A¡¢·ÖÁÑÄÜ> ³É¼üÄÜ B¡¢·ÖÁÑÄÜ> ³É¶ÔÄÜ

C¡¢·ÖÁÑÄÜ< µçÀëÄÜ D¡¢·ÖÁÑÄÜ< ³É¶ÔÄÜ

49£®ÏÂÁеç¶ÔÖÐ £¬±ê×¼µç¼«µçÊÆ ?´úÊýÖµ×î´óÕßÊÇ** £¨ £©

¦¨

A¡¢?(Ag+ / Ag) B¡¢?(Ag(CN)2/ Ag)

C¡¢?(Ag(NH3)2/ Ag) D¡¢?(AgI / Ag)

50£®ÔÚ pH£½9 ʱ £¬ÒªÊ¹ 0.10 mol?L£­1 ÂÁÑÎÈÜÒº²»Éú³É Al(OH)3 ³Áµí £¬ÔòNaF µÄŨ¶È

£¨mol?L£­1£©ÖÁÉÙÊÇ£¨Ksp Al(OH)3 £½ 1.3¡Á10£­33 £»KÎÈ [ Al F6 ]3£­ £½ 6.9¡Á1019 £©***

£¨ £©

¦¨

¦¨¦¨

??¦¨

A¡¢3.2 B¡¢0.32 C¡¢1.1 D¡¢0.11

51£®Ò»°ã²»ÄÜ×÷ΪÅäºÏÎïÖÐÐÄÔ­×ÓµÄÊÇ** £¨ £© A¡¢¸ßÑõ»¯Ì¬µÄ½ðÊô B¡¢¸ßÑõ»¯Ì¬µÄ·Ç½ðÊô

C¡¢¸ºÑõ»¯Ì¬µÄ½ðÊô D¡¢¸ºÑõ»¯Ì¬µÄ·Ç½ðÊô

52£®ÏÂÁÐÅäºÏÎïµÄÖÐÐÄÔ­×ÓµÄÅäλÊýÓдíÎóµÄÊÇ** £¨ £© A¡¢[ Co(NH3)3(NO3)3 ] B¡¢[ Co(NO2)2( en)2Cl2 ]

C¡¢K2[ Fe(NO)(CN)5 ] B¡¢[ Os( N2)2(NH3)4 ] Cl2

53£®ÔÚÅäÌ峡ӰÏìÏ £¬ÅäºÏÎïÖÐÐÄÀë× d Äܼ¶·¢Éú·ÖÁÑ¡£ÏÂͼËùʾµÄÕý·½Ðγ¡×÷ÓÃÏ £¬

ÄÜÁ¿×î¸ßµÄ d ¹ìµÀÊÇ** £¨ £©

z A¡¢d Z2 B¡¢d XY C¡¢d X2£­Y2 D¡¢d XZ x

y 54£®[ Co(NH3)6 ] 2£« ºÍ [ Co(NH3)6 ] 3£« µÄ³Éµ¥µç×ÓÊý·Ö±ðÊÇ** £¨ £© A¡¢1ºÍ 4 B¡¢3 ºÍ 4 C¡¢3 ºÍ 0 D¡¢0 ºÍ 3

55£®µç×ÓÅŲ¼Îª [Ar] t2g3 eg0 µÄ°ËÃæÌåÅäºÏÎïÊÇ*** £¨ £© A¡¢[ Mn Cl6 ] 4£­ B¡¢[ Cu Cl6 ] 4£­ C¡¢[ Co(CN)6 ] 3£­ D¡¢[ Cr F6 ] 3£­

56£®²¿·ÖÅäÌåµÄ¹â»¯Ñ§Ë³ÐòÊÇ £ºI£­ < Br£­ < Cl£­ < F£­ < H2O < NH3 < NO2< CN£­ £¬ÔòÏÂ

ÁÐ

? ÅäºÏÎïÖоßÓÐ×î´ó Dq ÖµµÄÊÇ** £¨ £©

A¡¢[ Mn(H2O)6 ] 2£« B¡¢[ MnBr6 ] 4£­

C¡¢[ Mn(NH3)6 ] 2£« D¡¢[ Mn(NO2)6 ] 4£­ 57£®ÔÚ¾§Ì峡ÖÐ £¬ÖÐÐÄÔ­×Ó d ¹ìµÀ·ÖÁÑͼΪ£º

a¡¢ £­ £­ d x2£­y2 , d z2 b¡¢ £­ £­ £­ d xy , d xz , d yz £­ £­ £­ d xy , d xz , d yz £­ £­ d x2£­y2 , d z2 c¡¢ £­ d x2£­y2

£­ d xy °´ËÄÃæÌ峡 ¡¢Æ½ÃæÕý·½Ðγ¡ ¡¢°ËÃæÌ峡µÄ´Î

£­ d z2 Ðò £¬·ÖÁÑͼÓ볡µÄÀàÐÍÒ»ÖµÄÊÇ*** £¨ £©

£­ £­ d xz , d yz

A¡¢a , b , c B¡¢c , a , b C¡¢c , b , a D¡¢b , c , a

58£®¾ßÓÐ×î´ó CFSE µÄËÄÃæÌåÅäºÏÎïÔ¤ÆÚÊÇ*** £¨ £© A¡¢[ TiCl4 ] B¡¢[ MnCl4 ] 2£­£¨HS£©

C¡¢[ FeCl4 ]£­£¨HS£© D¡¢[ CuCl4 ] 2£­ 59£®ÔÚÅäÌåNH3 £¬H2O £¬SCN

£¨ £©

A¡¢SCN£­ B¡¢NH3 C¡¢H2O D¡¢CN£­ 60£®ÒÑÖª £º Au3£« £« 3 e£­ £½ Au ?£½ 1.498 v

¦¨

£­

£¬CN

£­

ÖÐ £¬Í¨³£ÅäλÄÜÁ¦×îÇ¿µÄÊÇ*

[ AuCl4 ]£­ £« 3 e£­ £½ Au £« 4 Cl£­ ?£½ 1.00 v

¦¨

Ôò Au3£« £« 4 Cl£­ £½ [ AuCl4 ]£­ µÄÎȶ¨³£ÊýÊÇ*** £¨ £©