聚乙烯醇精馏一塔设计 下载本文

年产10000吨聚乙烯醇精馏塔系统的设计

3雾沫夹带

雾沫夹带的计算采用Hunt关联式[19]:

0.0057?u?eV????HT?hf对于单流型塔板:

u??? ??3.2VS,hf?2.5?hw?how?

AT?Af1)精馏段:u?0.569?0.543m/s,hf?2.5??0.05?0.0078??0.145m

1.130?0.0823.20.0057?0.543? ∴ eV????21.48?0.45?0.145? 2)提馏段:u'??0.0017m

0.647?0.617m/s,hf?2.5??0.05?0.0153??0.163m

1.130?0.0823.20.0057?0.617?' ∴ eV????17.97?0.45?0.163??0.0037m

二者的eV?0.1kg液/0.1kg气,故本设计中eV在允许范围内。 4 漏液点气速uom

对于筛板塔,漏液点气速uom可由下式来计算:

uom?4.4C0?0.0056?0.13hL?h???L?V

(1)精馏段:uom?4.4?0.76??0.0056?0.13?0.0578?0.0017??10262.73?6.93m/s

实际孔速u0?12.06m/s?uom 稳定系数K?u012.06??1.74?1.5 uom6.03'?4.4?0.76? (2)提馏段:uom?0.0056?0.13?0.0653?0.0014??10502.31?8.03m/s

'' 实际孔速u0 ?13.71m/s?uom 31

'u013.71 稳定系数K?'??1.71?1.5

uom8.03 故本设计中漏液点气速符合要求。 5液泛

为防止塔内发生液泛,降液管内液层高Hd应服从下式的关系,即

Hd???HT?hw?,Hd?hp?hL?hd??

?LS 其中液体流过降液管的局部阻力由hd?0.2??lh?wc2???计算,?很小,可忽略。 ?2?9.46?10?4? (1)精馏段:hd?0.2???0.78?0.0342???0.000252m液柱,则

?? Hd?0.0729?0.0578?0.000252?0.131m

取??0.5,则??HT?hw??0.5??0.45?0.05??0.25m?0.131m

?2.54?10?3?' (2)提馏段:hd?0.2???0.78?0.0365???0.00159m液柱,则

??2 Hd?0.0784?0.0653?0.00159?0.145m

''??0.5??0.45?0.05??0.25m?0.145m ?hw 取?'?0.5,则?'?HT 故本设计不会产生液泛。 3.4.7 塔板负荷性能图[20] 1.过量雾沫夹带线

以eV?0.1kg液/kg气为限,求VS?LS关系如下:

0.0057??uaeV????HT?hf (1)精馏段:ua?VS?0.954VS

1.130?0.0822/3?? ??3.2 how

2.84?3600LS???1.025???10000.78??32

?0.807LS2/3

年产10000吨聚乙烯醇精馏塔系统的设计

/3 hf?2.5hL?2.5?hw?how??0.125?2.0L2S

?0.954VS0.0057???? eV?2/3??21.48?0.45?0.125?2.0LS?3.2?0.1

整理得a线方程为:

/3 VS?2.18?13.38L2S

在操作范围内,任取几个LS值依上式计算得

LS VS

'a6?10?4 2.085

8?10?4 2.065

3.2?10?3

1.890

Vs'?0.954Vs' (2)提馏段:u?1.130?0.082' how?3600L'S2.84??1.041???0.781000?????2/32/3?0.820L'S

'''/3 h'f?2.5hL?2.5hw?how?0.125?2.1L2S

???0.954VS0.0057????? eV?2/3?19.97?0.45?0.125?2.1LS?3.2?0.1

整理得a'线方程为:

2/3 VS'?2.13?13.73L'S

在操作范围内,任取几个L'S值依上式计算得

L'S VS'

2.严重漏夜线 由uo,min?4.4C0VS,minA06.0?10?4 4.0?10?3 1.784

7.5?10?3 1.604

2.032

?0.0056?0.13hL?h???L?V,hL?hw?how,how

????2/3 uo,min?2.84?Lh?E?1000??lw

(1)精馏段:b线方程如下:

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VS,min2/3???2.84??1026?3600LS????0.0056?0.13??0.05??1.025?????0.0017??1000?0.78?????????2.73 ?4.4?0.76?0.063?0.749/3?0.15839.46L2?3.91S在操作范围内,任取几个LS值依上式计算得

LS VS

(2)提馏段:b'线方程如下

6?10?4 0.323

8?10?4 0.326

3.2?10?3

0.345

VS,min2/3???2.84??1050?3600LS????0.0056?0.13??0.05??1.041???0.0014????1000?0.78?????????2.31?4.4?0.76?0.063?0.749/3?0.15848.63L2?4.86S在

操作范围内,任取几个L'S值依上式计算得

L'S VS'

3.液相负荷下限线

6.0?10?4 4.0?10?3 7.5?10?3 0.410

0.360 0.390

对于平直堰,液相下限how?6mm为准,则how,min?6mm作为最小液体负荷标准,得:

how2.84?3600LS?E?1000??lw????2/30.78?6???LS,min???36002.84E??3/2?lw 3600得c和c'的方程式如下: (1)精馏段:LS,min6??????2.84?1.025?6?????2.84?1.041??3/2?0.78?6.41?10?4m3/s 36000.78?6.26?10?4m3/s 36003/2 (2)提馏段:L'S,min 4.液相负荷上限线

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