有机化学第五版下册(李景宁主编)-课后习题问题详解 下载本文

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CH3C6H5CH2CHCOOH(1)SOCl(2)NH3(3)Br2,OH-CH3C6H5CH2CHNH2S-(+)(-)

答案:

6. 完成下列反应: (1)

CH3((()))加热加热(1)CH3I(过量)??

NH(2)Ag2O,H2O1CH3I2Ag2O,H2O3?

(2)

CH3CH3?混酸Fe+HClNO2(CH3CO)2O??H+,H2O?NaNO2HCl??

(3)

CH3OCH3ONH2

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(4)

CH3_+CH2N(CH3)3Cl (5)

O2N

CH3O2NNH2

(6)

CH3CH2CH2NH2 (7)

BrNH

COHNO3AcOH?CH3

(8)

O2NFNO2H3C+ H2NONH?

(9)

OH3C+ NHH+?CH2CHCOOEt?H+?

(10)

H3CNCH3CH3O-

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答案: (1)

(注:书中有误,改为)

(2)

(3)

(4)

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(5).

(6)

(7)

BrNHNO2OCCH3

(8) (9)

CH3NCH3NCHCHCOOEtCH3NCH2CH2COOEt

(10)

CH3

7. 指出下列重排反应的产物: