大三上半学期有机化学章节试题含答?大学期末复习资料) - 百度文库 ر

ʮ

ҵ⡿

1. л

(1)H3CH3COCH3(2)OH2-׻-2,3-2-ϩ-5-

2. ûѧи黯

H2CCHCH2CH2OHɫɫBr2/CCl4LucasԼCH3CHCH2OH(1)CH3CH3CH2CHOHCH3CH3H3CCOHCH3²¼ӺDzɫɫ

3. зӦ

(1)CH2CHCH(CH3)2OHH+,CH=CHCH(CH3)2

(2)OH+H2SO4()

(3)OCH2CH3+HI(OH)+(CH3CH2I)(4)CH2CH2CH2OH(SOCl2)OHOCH2CH2CH2Cl(Na2CO3)OHO(5)OHOHH+()CH3OH3CCCCH3(6)CH3CH3H3CCOHCOHCH3H+(CH3)

17

༶ ѧ

4 ϳ

OH(1)̼µлϳCCH3CH3

BrMgOHHBr+MgBrCH3COCH3/+ H2O/HOHCCH3CH3

O(2)ɺϳCH2CH2CH3

OCH3CH2CH2MgBr/+ H2O/HHOCH2CH2CH3ŨH2SO4CH2CH2CH3B2H6-H2O2/OHCH2CH2CH3HO

OHCCH3CH33ɼC3лϳOCH3CClOCCH3CH3MgI/ѢH3O+ˮAlCl3CH3IMgOHCCH3CH3CH3MgI

ʮһ Ӻ

1. ϵͳдṹ

OH(1)HOOCCH3

OHO3-׻-5-ǻ-1-

(2)ǻͪ

2лǿ˳Ϊ b c d a

18

OHa.b.OHNO2c.OHd.OHNO2NO2NO2

3.лﰴǿ˳У(F) (C) (E) (D) (A) (B)

OH(A)(B)CH3OH(C)NO2OH(D)ClOH(E)OHCl(F)NO2OHNO2

4зӦ

OH(1)O+CH3CClOO( )AlCl3OHO( )

5Ʋṹ

һ㻯( A)ʽΪC7H8OƷѧӦŨHI(B)(C)(B)NaOH, FeCl3öɫCAgNO3ãɻɫ⻯д(A), (B), (C)Ĺʽ

A.OCH3B.OHC.CH3I

ʮ ȩͪ

1дṹʽ

19

༶ ѧ

NOH(1)(H3C)2CNNHNO2(2)NO2ͪ-2,4-(5)(3)OH2CCCCH2CH3H1ϩ3ͪͪ4-׻ͪNOH(4)OC2H5CH3CH2CHOC2H5ȩҴCH3

2зӦ

(1)CH3CH2CH2CHOCH3(2)ϡNaOHCH3CH2CH2CHCCHOLiAlH4CH2CH3H2OCH3ClZn-HgHClCH3CH2CH2CHCH3CCH2OHCH2CH3OCH3CH2CH2CˮAlCl3Br2( )COCH2CH2CH32C2H5OHHCl( )CH2CH2CH2CH3(3)(CH3)2CHCHO(CH3)2CCHO( )Br(CH3)2CCH(OC2H5)2BrCH3(CH3)2CCH(OC2H5)2(CH3)2CHCHO( )MgBr+ѢH3OOOMg(4)OϡNaOH( )( )(CH3)2CHCHCCHOOHCH3

3мС⣺

1ʻﰴ׺˼ӳɵĻԴ (A > B > D > C)

AClCH2CHOBBrCH2CHOCH2CCHCHODCH3CH2CHO

2лЩܷȩϡ·Ӧ绯ӦFehlingԼӦ

2лܷȩϵǣCEFH·ӦEGH绯ӦABDFehlingԼӦBCDEF

AECHOICH2CHOBHCHOFCH3CH2CHOC(CH3CH2)2CHCHOGCH3CH2CHCH3OHD(CH3)3CCHOHCOCH3

3лܷ·Ӧǣ a c f g 뱥NaHSO3ˮҺӳ

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